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Nitrogen makes up about 78% of the atmosphere by volume but the
atmosphere of Mars contains less than 3% nitrogen. The element seemed so
inert that Lavoisier named it azote, meaning "without life".
However, its compounds are vital components of foods, fertilizers, and
explosives. Nitrogen gas is colorless, odorless, and generally inert. As a
liquid it is also colorless and odorless.
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It was known during the 18th
century that air contains at least two gases, one of which supports
combustion and life, and the other of which does not. Nitrogen was discovered
by Daniel Rutherford in 1772, who called it noxious air, but Scheele,
Cavendish, Priestley, and others at about the same time studied
"burnt" or "dephlogisticated" air, as air without oxygen
was then called.
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While about one fifth of the
atmosphere is oxygen gas, the atmosphere of Mars contains only about
0.15% oxygen. Oxygen is the third most abundant element found in the sun, and
it plays a part in the carbon-nitrogen cycle, one process responsible for
stellar energy production. Oxygen in excited states is responsible for the
bright red and yellow-green colors of the aurora. About two thirds of the
human body, and nine tenths of water, is oxygen. The gas is colorless,
odorless, and tasteless. Liquid and solid oxygen are pale blue (see picture
above) and strongly paramagnetic (contains unpaired electrons).
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Oxygen is very reactive and
oxides of most elements are known. It is essential for respiration of all
plants and animals and for most types of combustion.
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Leonardo da Vinci suggested that
air consists of at least two different gases. Before then, air was felt to be
an element in its own right. He was also aware that one of these gases
supported both flames and life. Oxygen was prepared by several workers before
1772 but these workers did not recognize it as an element. Joseph Priestley
is generally credited with its discovery (who made oxygen by heating lead or
mercury oxides), but Carl Wilhelm Scheele also reported it independently.
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The behavior of
oxygen and nitrogen as components of air led to the advancement of the
phlogiston theory of combustion, which influenced chemists for a century or
so, and which delayed an understanding of the nature of air for many years.
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Ozone (O3)
is another allotrope of oxygen. It is formed from electrical discharges or
ultraviolet light acting on O2. It is an important component of
the atmosphere (in total amounting to the equivalent of a layer about 3 mm
thick at ordinary pressures and temperatures) which is vital in preventing
harmful ultraviolet rays of the sun from reaching the earth's surface. Undiluted ozone is bluish in color.
Liquid ozone is bluish-black, and solid ozone is violet-black.
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