NATS 101-05
Lecture 7

Atmospheric Moisture:
Water vapor
Condensation &
Cloud Formation

Hydrological Cycle
Humid Air
Humid air is a mixture of molecules that make up dry air (mostly N2 and O2) and lighter water vapor (H2O) molecules.
Each type of molecule contributes a fraction of total air pressure, or a partial pressure, proportional to the number molecules per unit volume. The partial pressure of water vapor is termed the vapor pressure.

Saturation Vapor Pressure
The partial vapor pressure at which the
rate of evaporation equals the rate of condensation in a closed system is called the saturation vapor pressure or SVP.
The SVP effectively denotes the maximum water vapor that air the can ŇholdÓ.
SVP depends strongly on temperature.
Vapor pressure and SVP provide a measure of the actual water vapor content and the airŐs potential capacity, respectively.

Slide 5
SVP and Temperature
SVP nearly doubles with a 10oC warming
SVP and T Graph
Supercooled water droplets can exist to temps of -40oC
For temps below 0oC, SVP runs 10%-30% lower over ice

Relative Humidity
Air with a RH=100% is said to be saturated.
RH depends on air temperature (SVP).
RH changes by either changing airŐs water vapor content or the airŐs temperature.

Relative Humidity
Relative Humidity
(Ahrens, Appendix B)
Consider air that is saturated at 0oC
Temp VP   SVP RH
  0oC 6 mb   6 mb 100%
10oC 6 mb 12 mb 50%
20oC 6 mb 23 mb 28%
30oC 6 mb 42 mb 14%
40oC 6 mb 68 mb    9%

Other Measures of Humidity
Dew Point
DP-temperature to which air must be cooled at constant pressure to become saturated (at which point dew forms).
Higher DP Þ Higher water vapor content.
DP is a good indicator of the actual water vapor content since air pressures vary very little along the earthŐs surface.
DP is plotted on surface weather maps.
DP depression (Temp-DP) is plotted aloft.

Arizona Dew Point Ranges
Vapor Pressure Dew Point
24 mb 20oC
12 mb 10oC
  6 mb    0oC
    3 mb -10oC

Wet Bulb Temperature
Wet Bulb Temp -Lowest temp to which air can be cooled by evaporation of water into it.
Warmer than dew point since moisture is being added to air which raises dew point.
Measured with sling psychrometer.

Wet Bulb Temperature
(Ahrens, Appendix D)
Wet bulb temperature lies about 30% of the way from the dew point to the temperature
Application-Wet bulb temp gives maximum possible efficiency for a swamp cooler
  Month MAX Dew P Wet Bulb June 100oF 37oF    65oF       July 100oF 63oF    75oF

Heat Index
Humid Air is Less Dense
Slide 17
Summary: Moisture
Water vapor comes from the evaporation of sea water and resides in the atmosphere for ~1 week.
Air has a saturation level for water vapor
Saturation level depends on air temperature
Humid air is slightly less dense than dry air
Water vapor content can be quantified by         RH, dew point temp, wet bulb temp

NowÉCondensation:
Fog Formation

Cloud Condensation Nuclei
Small, airborne particles are necessary on which water vapor can condense to produce cloud droplets
Without such particles, RH>100% would be needed to produce clouds
Such surfaces are called Cloud Condensation Nuclei (CCN)
CCN are light and stay suspended for days

Cloud Condensation Nuclei
Sources
Dust, volcanic ash, smoke, soot, salt, sulfate particles
Concentrations
1,000-10,000 per cc Highest over cities Highest at surface

Cloud Condensation Nuclei
Haze over Melting Snow
Condensation
When air becomes supersaturated from either the temperature cooling or the addition of water vapor, water condenses onto CCN as small cloud droplets
Diameters of droplets are 2-20 microns, (10-100 times smaller than human hair)
Concentrations are 50-1,000 droplets per cc

Size of Cloud Droplets
What is Fog?
Fog - a cloud at the ground
There are four basic types of fog
Radiation Fog
Advection Fog
Upslope Fog
Steam Fog
Combinations exist (Radiation-Advection)

Radiation or Ground Fog
Valley Fog
Radiation Fog in Valley
Fog Dissipation in the Morning
Advection Fog
Advection Fog at Golden Gate
Upslope Fog
Steam Fog or Sea Smoke
Why You See Your Breath        on a Cold Winter Night
Condensation can occur if moist, warm air mixes with cold, dry air.
Temp RH SVP VP
Air 0oC 20% 6 mb 1 mb
(clear)
Breath 36oC 80% 63 mb 55 mb
(clear)
50-50 18oC 140% 20 mb 28 mb (cloud)
90-10 4oC 90% 8 mb 6 mb
(clear)
The 50-50 mix condenses into a cloud that quickly evaporates as your exhalation is diluted further

Steam Fog over Thermal Pool
Precipitation or Frontal Fog
Number of Days with Fog
Summary: Condensation
Condensation
Can occur by cooling or moistening of air
CCN permit condensation at RH near 100%
Small (<0.2 to 1 microns) airborne particles
Responsible for Haze formation at RH < 100%

Summary: Fog
Fog - a cloud at the ground
Composed of small (20 micron) water drops
Four primary types of Fog
Radiation-Advection-Upslope-Steam
Occur under distinct weather conditions

Next Lecture Assignments
Topic - Cloud Formation and Types
Reading - Ahrens pages 89-105
Problems - 4.3, 4.13 - 4.16