We did cover a little course material in class today just so you
can get an idea of how that will work. If we
were using a book we'd start in Chapter 1 and here's some of what we
would be looking at first in this course.
We
had enough time
today
to
look at the first question, the composition of
the atmosphere. Here are a few questions to get you thinking
about the air around you.
Can
you
see
air?
This is a little
more detailed
answer to this question than was given in class. Air is
normally clear, transparent, and invisible (that would be true of the
air in the
classroom). Sometimes the air looks
foggy, hazy or smoggy. In these cases you are seeing the effects
of
small water droplets or ice crystals (fog) or small particles of dust
or smoke (haze and smog). The particles themselves may be too
small
to be seen with
the naked eye but are visible because they scatter (redirect)
light. Scattering is a pretty important concept and we will learn
more about it in a week
or so.
The atmosphere isn't actually clear. When sunlight shines
through the atmosphere the sky appears blue. This is a little
more
complicated form of scattering of sunlight by air molecules.
We'll come back to this later as well.
Can
you
smell
air?
I
don't think you can smell or taste air (air containing nitrogen,
oxygen, water vapor, argon and carbon dioxide) though, as a student
pointed out, this might just be because we are so used to it.
Some pollutants do have a smell. And I suspect our sense is
sensitive enough for us to
detect certain air pollutants even when
their concentration is very small (probably a good thing because many
of them are poisonous). There
are also lots of other odors you
can sometimes smell (freshly cut grass, hamburgers on an outdoor grill,
etc) but I don't consider these normal constituents of the atmosphere.
Someone
in the other section of the class mentioned natural
gas (methane) used in hot water heaters, some stoves, and
furnaces. Because methane is
odorless, a chemical (mercaptan) is added so that you can smell it and
know when there is a leak before it builds
up a concentration that could cause an explosion.
Can
you
feel
air
It
is harder to answer this question. We're always in contact with
air. Maybe we've grown so accustomed to it we aren't aware of how
it feels. We can certainly feel whether
the air is hot or cold, but that have more to do with energy exchange
between us and our surroundings. And we can feel wind.
We will see that here in the
classroom air pressure is
pressing on
every square
inch of our bodies with 12 or 13 pounds of force. If that were to
change suddenly I'm pretty sure we'd feel it and it would probably
really hurt.
What
are
the
5
most
abundant
gases
in
air?
Let's start with the most abundant gas in the
atmosphere.
A lot of people seemed to know this is nitrogen. I poured some liquid nitrogen into a
styrofoam
cup. Here's a photo I took back in my office.
You can see the liquid, it's clear, it looks like water.
We'll
use
liquid
nitrogen
in
several class
demonstration this semester. Once the liquid nitrogen
evaporates and turns into a gas it is invisible.
Nitrogen was
discovered in 1772 by Daniel Rutherford (a Scottish
botanist). Atmospheric nitrogen is relatively unreactive
and is sometimes used to replace air in packaged foods to preserve
freshness.
Oxygen
is
the second most abundant gas in the atmosphere. Oxygen is the
most abundant element (by mass) in the earth's crust, in ocean water,
and in the human body.
A couple of photographs of liquid oxygen are shown above.
It has a (very faint) blue
color (I was pretty disappointed when I saw the pictures for the first
time because I had imagined the liquid oxygen might be a deep vivid
blue).
When heated (such as in an automobile engine) the oxygen and
nitrogen in air react
to form compounds such as nitric oxide (NO), nitrogen dioxide (NO2),
and
nitrous
oxide
(N2O). Together as a group these are
called oxides of nitrogen; the first two are air
pollutants, the
last is a greenhouse gas.
Here are the 5 most abundant gases
in the earth's atmosphere.
Water vapor and argon are the 3rd
and 4th most abundant
gases in the
atmosphere. A 2% water vapor concentration is listed above but it
can vary from near
0% to as high as 3% or 4%. Water vapor is, in many locations, the
3rd
most abundant gas in air. In Tucson most of the year, the air is
dry enough
that argon is in 3rd position and water vapor is 4th.
Water vapor, a gas, is
invisible. Clouds are visible because they are made up of small
drops of liquid
water or ice crystals. We can see clouds even though the
individual water droplets are too small to be seen because they scatter
light. Water is the only compound that exists
naturally in solid, liquid, and gaseous phases in the atmosphere.
Argon is an unreactive noble gas (helium, neon, krypton, xenon, and radon are also inert gases).
Here's a little more
explanation (from Wikipedia)
of
why
noble
gases
are
so
unreactive.
Don't
worry
about
all
these
additional
details.
The
noble
gases
have
full valence
electron shells. Valence electrons
are the outermost electrons of an atom and are normally
the only electrons that participate in chemical bonding.
Atoms with full valence electron shells are extremely stable and
therefore do not tend to form chemical bonds and have little tendency
to gain or lose electrons.
Noble gases are often used used in neon signs;
argon produces a blue color. The colors produced by Argon (Ar),
Helium (He),
Kryton (Kr), Neon (Ne) and Xenon (Xe), which are also noble gases, are
shown above (source of the images).
This picture
wasn't shown in class.
Water
plays an important role in the formation of
clouds,
storms,
and weather. Meteorologists are very interested in knowing and
keeping track of how
much water vapor is in the air at a particular place and time.
One of the variables they use is the dew point temperature. The
value
of
the
dew
point
gives
you
an
idea
of
how
much
water
vapor
is
actually
in
the
air.
The
higher
the
dew
point
value,
the
more
water
vapor the higher the water vapor
concentration.