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Tracking Water Vapor in the Atmosphere

air parcel A "Parcel of Air" is an iminaginary body of air about the size of a large balloon that is used to explain the behavior of air. We will describe what is meant by the relative humidity and dew point temperature of air in a parcel. The parcel concept is used because we often would like to know what will happen to air as it moves in the atmosphere, and air tends to move together in blobs about the size of parcels (not molecule by molecule). The parcel concept will be extemely important in describing cloud and thunderstorm formation. For one thing, we will want to keep track of the relative humidity in an air parcel as it moves up and down in the atmosphere.

Relative Humidity

The relative humidity in an air parcel is defined as the ratio of the amount of water vapor actually in the air to the maximum amount of water vapor required for saturation at a particular temperature

water vapor content
Relative humidity RH =
water vapor capacity

For example, air with a 50 percent relative humidity actually contains one-half the amount of water vapor required for saturation. Air with a 100 percent relative humidity is said to be saturated because it is filled to capacity with water vapor.

One way to compute relative humidity is to take the ratio of the actual vapor pressure (e) in a parcel (measured) with the saturation vapor pressure (es) at the parcel temperature, or RH = e/es. However, following meteorological convention, we will use something called Mixing Ratio (U) instead of vapor pressure.

actual (measured) mass of water vapor (in parcel) in grams
Mixing Ratio U =
mass of dry (non water vapor) air (in parcel) in kilograms

We will use the mixing ratio of keep track of the amount of water vapor in air parcels ... the greater the mixing ratio, the more water vapor that is in the air. We will use the Saturation Mixing Ratio (Us) to tell us the maximum amount of water vapor that can be in the air.

mass of water vapor required for saturation (in parcel) in grams
Saturation Mixing Ratio Us =
mass of dry (non water vapor) air (in parcel) in kilograms

The Relative Humidity (RH) is simply the mixing ratio divided by the saturation mixing ratio.

actual (measured) water vapor content U
Relative Humidity RH =
=
maximum possible water vapor amount (saturation) Us

You are expected to know this equation for relative humidity and to be able to use it to solve simple problems. Just as with saturation vapor pressure, the saturation mixing ratio, which specifies the maximum amount of water vapor that can be in the air, is determined by the air temperature ... the higher the air temperature, the greater the saturation mixing ratio. We will use pre-computed tables of saturation mixing ratio to help solve problems. You should open the tables and make sure you understand the relationship between air temperature and the saturation mixing ratio, which is, as the air temperature increases, the saturation mixing ratio increases rapidly (exponentially). When using these tables make sure to use the correct temperature table, Fahrenheit or Celsius.

Let's go through an example.

A. What is the RH of an air parcel with a temperature of 25°C and a water vapor mixing ratio of U = 8 g/kg?

B. Continuing the example. What will the RH of the air in the parcel be if the parcel is cooled to T = 15°C with no change in the water vapor content?

We can see that RH by itself does not indicate the actual amount of water vapor in the air because it has a dependence on the air temperature. In the example above, even though the actual amount of water vapor in the air was the same in parts A and B, the relative humidity was different because Us changed due to the temperature change. In fact there are two ways RH can change: (1) Change the water vapor content of the air (changes the mixing ratio, U, which is the numerator of the RH equation) and (2) Change the temperature of the air (changes the saturation mixing ratio, Us, which is the denominator of the RH equation).

Most people use Relative humidity to describe the water vapor content of the air, but it is widely misunderstood. Relative humdity in itself does not indicate the actual amount of water vapor in the air because it depends on temperature. For example, an air parcel at a temperature of 10°C with RH = 100% contains less water vapor than an air parcel at a temperature of 25°C with RH = 50%. You should be able to convince yourself of this by using the relative humidity equation and the table of saturation mixing ratios.

Dew point

The dew point temperature (Td) is defined as the temperature to which an air parcel would have to be cooled (with no change in its water vapor content) in order for it to be saturated with water vapor. It is determined by the amount of water vapor in the parcel, i.e., as the mixing ratio, U, increases, the dew point temperature, Td increases. If you know the actual mixing ratio in an air parcel, you can use the table of saturation mixing ratios to get the dew point temperature.

The dew point temperature is the answer to this question: "Given the amount of water vapor that is in a parcel, what would the air temperature have to be for the parcel to be saturated with that amount of water vapor?" The dew point temperature does indicate the actual vapor content of the air: the higher the dew point, the more water vapor in the air. You should realize that the dew point temperature is not something that is measured with a thermometer. It is really used to indicate the amount of water vapor that is in the air.

You are expected to be able to use the Relative Humidity equation and the table of saturation mixing ratios to perform simple calculations of dew point temperature. So far we have used the saturation mixing ratio tables to correspond air temperature in the left hand column with the saturation mixing ratio in the right hand column. The saturation mixing ratio tables are also be used to correspond the dew point temperature, Td in the left hand column with the mixing ratio, U, in the right hand column. In other words the actual amount of water vapor in the air can be specified using the mixing ratio or the dew point temperature.

Dew point temperature calculation example.

If the air temperature is T = 10°C and the relative humidity is RH = 50%, what is the dew point temperature, Td?

The difference between air temperature and dew point temperature can indicate whether the relative humidity is low or high.

Normally, near the Earth's surface, the relative humidity is less than 100%, therefore, net evaporation is occurring since the rate of evaporation is faster than the rate of condensation. To convince yourself of this, leave out an uncovered glass of water. The water will eventually evaporate. In fact the lower the relative humidity, the faster the rate of net evaporation. Once evaporated from the surface, water vapor moves around with the rest of the air.

Occasionally, there may be net condensation occurring near the Earth's surface. If air near the ground is cooled below its original dew point temerature, fog will result. Fog is nothing more than a cloud at ground level. We will talk more about clouds soon. Beside fog, are there ever situations near the Earth's surface when net condensation occurs? ANSWER: Yes, dew and frost. When an object becomes colder than the dew point temperature, the air in contact with that object becomes colder than the dew point temperature, resulting in net condensation:

An everyday example is condensation that happens on the outside of a cold can of soda or a glass of ice water. The water that you see came from the air as water vapor condensed into liquid. It tells you that the can must be colder than the dew point temperature of the air. Here in the desert, where the dew point temperature is often well below 0° C, you will not always get condensation on the sides of a cold can of soda. But in a more humid climate where the dew point is higher, you will see this type of condensation more often.

As mentioned above, the dew point temperature is a measure of the amount of water vapor that is in the air. So if you wanted to compare the amount of water vapor in the air at two different locations, the one with the higher dew point temperature has the greater water vapor content. A graph of the dew point temperature with time indicates how the amount of water vapor in the air changes at a fixed location. Often there is an increase in dew point temperature just before and after a rain event.

A couple of links to dew point information:

dew point temperature and relative humidity on the Univ. of Arizona campus over the last 24 hours. Click on the weekly or monthly plots at the bottom of the page to see a longer time series of changes in dew point temperature. Look at how the dew point temperature and relative humidity change on days when precipitation was measured on campus.

U.S. map of current dew-point temperature. Using the map, the locations with the higher dew point temperatures have more water vapor in the air. However, the map does not indicate much about the relative humidity around the United States. Why not? Or what other information would you need to be able to determine values of relative humidity?

Summary for how Water Behaves Based on Relative Humidity

You should understand the points made below. You can apply these points to explain what will happen under conditions where the relative humidity is known.


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