Tuesday Feb. 17, 2009

A new homework assignment was handed out in class today.  You can download it here.

We will be covering the topic of cloud electrification this week.  First we need to do a little review.  We will start with the microphysical structure of a cold thunderstorm cloud.  Cold refers to the fact that much of the cloud is found at high enough altitude that it is at below freezing temperatures and contains ice crystals.  This is the case for thunderstorm clouds even in Tucson on the hottest day of the summer.


The important part of the cloud,  both for precipitation formation and electrification , is the middle mixed phase region.  There you find ice crystals and lots of supercooled water droplets (water cooled to below freezing that is unable to freeze).

The formation of water droplets does not occur as you might have imagined.  You might have thought that once the RH reaches 100% that water vapor would simply condense and form little droplets.


But actually it is hard to form small droplets.  This is because small droplets evaporate at a high rate due to the curvature effect (the blue arrows above represent evaporation, the red arrows condensation)

It is much easier for droplets to form when water vapor condenses onto small particles in the air called condensation nuclei.  The droplets start large enough that the curvature of the water surface doesn't affect the rate of evaporation.  Condensation nuclei are plentiful even in clean air, where they are typically found in concentrations of 100s per cubic centimeter.

Condensation nuclei can play an additional role when they dissolve in water.


The resulting solution has a lower rate of evaporation than a droplet composed of pure water.  Droplets can begin to form before the relative humidity reaches 100%.



Ice crystal nuclei also make it easier for ice crystals to form by deposition (deposition is a gas to solid phase change) or by freezing of water droplets.  Ice crystal nuclei are however relatively scarce.  This is because the nucleus must be composed of a material with a crystalline structure that resembles ice.  Silver iodide works well as an ice nucleus, so does kaolinite (a type of clay or mineral), I believe.


Ice crystals evaporate (actually they sublimate) at a slower rate than water droplets.  Because the surrounding air is moist enough to keep the water droplets in equilibrium (3 arrows of condensation balancing 3 arrows of evaporation in the figure above), and because water vapor will condense onto the ice crystals at the same rate, the ice crystals will grow and become snow crystals.  Have a look at photomicrographs of some snow crystals at www.snowcrystals.com.



In this figure, a falling snow crystal is colliding with supercooled water droplets.  They stick to the crystal and freeze.  This process is called accretion or riming.  If this goes on long enough the original snow crystal can get completely covered with frozen water droplets.  The resulting precipitation particle is called graupel.  It is often mistaken for hail.




This figure shows the common distribution of electrical charge in a mature thunderstorm.  The structure is tripolar and consists of an upper positive charge center (1b), a lower layer of negative charge (1a), and smaller lower positive charge centers (1c).  Screening layers form around the edges of the cloud (2a & 2b).    Strong electrical fields may cause pointed objects on the ground to go into corona discharge and fill the air above the ground with positive space charge (3).


The layer of negative charge in thunderstorms seems to always be found in the -10 to -30 C temperature range.


The distribution of charge in thunderstorms is often much more complex than the simple tripolar model discussed above.


We had just enough time at the end of the class to look at one of the processes that may cause clouds to become electrified.

In the convective theory, positive space charge between the cloud base and the ground is carried upward into the cloud by the updraft.  Negative charge carriers in the surrounding air are drawn to the positive charge in the top of the cloud and form a screening layer.  Cloud edge motions carry this negative charge down and into the middle center of the cloud to form the main negative charge center.  The electric field at the ground intensifies because of the close proximity of negative charge in the cloud.  Objects on the ground go into corona discharge and "spray" positive charge into the air.  The convective theory is generally not considered to be a viable mechanism for the initial electrification of thunderstorms.