Wednesday Feb. 2, 2011
click here to download today's notes in a more printer friendly format

Three songs from the Fleet Foxes before class today ("White Winter Hymnal", "Tiger Mountain Peasant Song", "Mykonos")

The 1S1P Bonus Assignment reports have been graded.  The score at the top of your paper will look something like this:




The first number is the content grade (up to 6 pts possible), the second is the writing quality grade (4 pts possible).  Don't think of this as 85% (a B).  Rather you now have 8.5 pts towards your goal of earning 45 pts by the end of the semester.

Some really cold weather is expected tonight and Thursday night.  I may be in a very bad mood on Friday if all the plants in my vegetable garden freeze.  Brocolli, lettuce, and spinach on the left picture below, snowpeas and carrots on the right.




    
Thursday morning update.  Everything in the garden was frozen stiff this morning (I brushed up against one of the brocolli plants and part of a leaf just broke off).  We'll just have to wait until everything thaws out to see whether they recover or are just dead.  I probably won't know that until the weekend.  So I'm postponing the bad mood until next week.


Today before the Practice Quiz: the Ideal Gas Law

It is the first step in understanding better why warm air rises and cold air sinks.



Hot air balloons rise (they also sink), so does the relatively warm air in a thunderstorm (its warmer than the air around it).   Conversely cold air sinks.  The surface winds caused by a thunderstorm downdraft (as shown above) can reach speeds of 100 MPH and are a serious weather hazard.

A full understanding of these rising and sinking motions is a 3-step process (the following is from the bottom part of p. 49 in the photocopied ClassNotes)


Well only have time today to learn about the ideal gas law.  That is an equation that tells you which/how properties of the air inside a balloon work to determine the air's pressure.  On Friday we will look at Charles' Law, a special situation involving the ideal gas law (air temperature and density change together in a way that keeps the pressure inside a balloon constant).  We'll also learn more about the vertical forces that act on air (the downward gravity force and the upward pressure difference force)

Students working on Experiment #1 will need to understand the ideal gas law to be able to explain why/how their experiment works.

The figure above makes an important point: the air molecules in a balloon "filled with air" really take up very little space.  A balloon filled with air is really mostly empty space.  It is the collisions of the air molecules with the inside walls of the balloon that keep it inflated.



Up to this point in the semester we have been thinking of pressure as being determined by the weight of the air overhead.  Air pressure pushes down against the ground at sea level with 14.7 pounds of force per square inch.  If you imagine the weight of the atmosphere pushing down on a balloon sitting on the ground you realize that the air in the balloon pushes back with the same force.  Air everywhere in the atmosphere pushes upwards, downwards, and sideways. 

The ideal gas law equation is another way of thinking about air pressure, sort of a microscopic scale version.  We ignore the atmosphere and concentrate on just the air inside the balloon.  We are going to "derive" an equation.  Pressure (P) will be on the left hand side.  Relevant properties of the air inside the balloon will be found on the right side of the equation.





In A
the pressure produced by the air molecules inside a balloon will first depend on how many air molecules are there, N.  If there weren't any air molecules at all there wouldn't be any pressure.  As you add more and more add to something like a bicycle tire, the pressure increases.  Pressure is directly proportional to N; an increase in N causes an increase in P.  If N doubles, P also doubles (as long as the other variables in the equation don't change).

In B
air pressure inside a balloon also depends on the size of the balloon.  Pressure is inversely proportional to volume, V .  If V were to double, P would drop to 1/2 its original value.

Note
it is possible to keep pressure constant by changing N and V together in just the right kind of way.  This is what happens in Experiment #1 that some students are working on.  Oxygen in a graduated cylinder reacts with steel wool to form rust.  Oxygen is removed from the air sample which is a decrease in N.  As oxygen is removed, water rises up into the cylinder decreasing the air sample volume.  N and V both decrease in the same relative amounts and the air sample pressure remains constant.  If you were to remove 20% of the air molecules, V would decrease to 20% of its original value and pressure would stay constant.



Part C: Increasing the temperature of the gas in a balloon will cause the gas molecules to move more quickly.  They'll collide with the walls of the balloon more frequently and rebound with greater force.  Both will increase the pressure.  You shouldn't throw a can of spray paint into a fire because the temperature will cause the pressure inside the can to increase and the can could explode. 

Surprisingly, as explained in Part D, the pressure does not depend on the mass of the molecules.  Pressure doesn't depend on the composition of the gas.  Gas molecules with a lot of mass will move slowly, the less massive molecules will move more quickly.  They both will collide with the walls of the container with the same force.

The figure below (which replaces the bottom of p. 51 in the photocopied ClassNotes) shows two forms of the ideal gas law.  The top equation is the one we just derived and the bottom is a second slightly different version.  You can ignore the constants k and R if you are just trying to understand how a change in one of the variables would affect the pressure.  You only need the constants when you are doing a calculation involving numbers (which we won't be doing).





We spent the rest of the class period on the Practice Quiz.  You can download a copy here is you didn't take it.  And here are the answers to the questions.