In Charles Law we assume that the
pressure of a parcel of air will remain constant (parcel is just
another word for volume). Changing the temperature of a volume of
air will cause a change in density and volume and pressure will stay
constant. This is an important situation because this is how
volumes of air in the atmosphere behave.
The explanation
below is a little more detailed and more carefully illustrated version
of what was done in class.
We start with a balloon of air. The air inside and outside
the balloon (or parcel) are exactly the same.
Note the pressure pushing inward is balanced by the pressure of the air
inside the balloon that is pushing outward. If we change
something inside the balloon that upsets this pressure balance, the
balloon would expand or shrink until the pressures were again in
balance.
Volumes of air in the atmosphere will always try to keep the
pressure of the air inside the parcel constant (P
inside is always trying to stay equal to P outside). That's why
we say air in the atmosphere obeys Charles' Law.
First let's imagine warming the air inside a balloon. We'll won't
change the temperature of the air outside the balloon.
Increasing the temperature will momentarily increase the
pressure. This creates an imbalance. Now that P inside is
greater than P outside the
balloon will expand.
Increasing the volume causes the pressure to start to decrease.
The balloon will keep expanding until P inside is back in balance
with P outside.
We're left with a balloon that is larger, warmer, and filled with lower
density air than it was originally.
The pressures inside and outside are again the same. The pressure
inside is back to what it was before we warmed the air in the
balloon. You can increase the temperature and volume
of a parcel together in a way that keeps pressure constant (which is
what Charles' law requires). Or you can increase the temperature
and decrease the density together and keep the pressure constant.l
We can go through the same kind of reasoning and see what happens
if we cool the air in a parcel. I've included all the steps
below; that wasn't done in class.
We'll start with a parcel of air that has the same temperature and
density as the air around it.
We'll cool the air inside the parcel. The air outside stays
the same.
Reducing the air temperature causes the pressure of the air inside
the balloon to decrease. Because the outside air pressure is
greater than the pressure inside the balloon the parcel is compressed.
The balloon will get smaller and
smaller (and the pressure inside will get bigger and bigger) until the
pressures inside and outside the balloon are again equal. The
pressure inside is back to the value it had before you cooled the air
in the parcel.
If you want to skip all the details and just remember one thing,
here's what I'd recommend (a statement that I
didn't show in class)
Charles
Law can be demonstrated by dipping a balloon in
liquid
nitrogen. You'll find an explanation on the top of p. 54 in the
photocopied ClassNotes.
The balloon shrinks down to practically nothing when dunked in the
liquid nitrogen. It is filled with very cold, very high density
air. When the balloon is pulled from the liquid nitrogen and
starts to warm up it expands. Density in the balloon
decreases. The volume and temperature keep changing
in a way that kept pressure constant (pressure inside the balloon is
staying equal to the air pressure outside the balloon).
Eventually the balloon ends
up back at room temperature (unless it pops while warming up).
Step #3 Vertical forces acting on parcels of air
And finally the last step toward understanding why warm air rises
and cold air sinks. We'll have a look at the forces that act on
parcels of air in the atmosphere. This information is
found on p. 53
in the photocopied
ClassNotes.
Basically it comes down to this - there are two forces
acting on a parcel of air in
the atmosphere. They are shown on the left hand side
of the figure above.
First is gravity, it pulls downward. The strength of the gravity
force
(the weight of the air in the parcel) depends
on the mass of the air inside
the parcel.
Second there is an upward pointing pressure difference force.
This
force is
caused by the air outside
(surrounding) the parcel. Pressure decreases with increasing
altitude. The pressure of the air at the bottom of a parcel
pushing upward is slightly stronger than the pressure of the air at the
top of the balloon that is pushing downward. The overall effect
is an upward pointing force.
When the air inside a parcel is exactly the same as the air
outside,
the two forces are equal in strength and cancel out. The parcel
is
neutrally bouyant and it wouldn't rise or sink, it would just sit in
place.
Now have a look at the right hand side of the figure.
If you replace the air inside the balloon with warm low density
air, it
won't weigh as much. The gravity force is weaker. The
upward
pressure difference force doesn't change (because it is determined by
the air outside the balloon which hasn't changed) and ends up stronger
than the
gravity force. The balloon will rise.
Conversely if the air inside is cold high density air, it weighs
more. Gravity is stronger than the upward pressure difference
force and the balloon sinks.
It all comes down to how the density of the in parcel compares to
the density of the air surrounding the parcel. If the parcel is
filled with low density air it will rise. A parcel full of high
density air will sink.
We did a short demonstration to show how density can
determine
whether an object or a parcel of air will rise or sink. We used
balloons filled with helium (see bottom of p. 54 in
the photocopied Class
Notes). Helium is less dense than air even when it has the same
temperature as the surrounding air. A
helium-filled balloon doesn't need to warmed up in order to rise.
We dunked the helium-filled balloon
in some liquid nitrogen to cool
it
and to cause the density of the helium to increase. When
removed
from the liquid nitrogen the balloon didn't rise, the gas inside was
denser than the surrounding air (the purple and blue balloons in the
figure above). As the balloon warms and expands
its density decreases. The balloon at some point has the same
density as the air around it (green above) and is neutrally
bouyant (it's still cooler than the surrounding air). Eventually
the balloon becomes less dense that the
surrounding air (yellow) and floats up to the ceiling (which in ILC 150
is about 30 feet high)
Something like this happens in the
atmosphere.
Sunlight shines through the atmosphere. Once it reaches the
ground at (1) it is absorbed and warms the
ground. This in turns warms air in contact with the ground
(2) As this air warms, its density starts to decrease. When
the air density is low enough,
small "blobs" of air separate from the air layer at the ground and
begin
to rise, these are called "thermals." (3) Rising air expands and
cools (we've haven't covered
this yet and it might sound a little contradictory). If it cools
enough (to the dew point) a cloud will
become visible as shown at Point 4. This whole process is called
free convection; many of our summer
thunderstorms start this way.